Our 3000 series colors were designed for use a wide
range of the firing temperature to get a stable color
tone and good chemical durability.
Also, classified into
(C)type : Cadmium bearing and
(N)type : Normal Cadmium free colors.
We recommend you to mix (C) and (C) type or (N) and (N) type by mixing ratio to meet your specific color match.
The firing range of 3000 series is recommended 780~830?
* Pb and Cd detection testing:
Immerse the fired color of decorated ware in 4% acetic acid (CH3COOH) for 24 hours
by the automatic absorption spectroscopy.
* Result of chemical resistance test ( Surface area : 0.1dm2, Volume : 35ml )
Color Number :
3150 (C) Red : Pb 0.3274 ppm, Cd 0,2351 ppm
3243 (N) Yellow : Pb 0.0889 ppm, Cd 0.0098 ppm
3313 (C) Mixing White : Pb 0.1375 ppm, Cd 0.0132 ppm
3366 (N) Mixing White : Pb 0.2522 ppm, Cd 0.0157 ppm
3486 (N) Green : Pb 0.3032 ppm, Cd 0.0186 ppm
3589 (N) Cobalt Blue: Pb 0.6608 ppm. Cd 0.0217 ppm
3562 (N) Purple Blue: Pb 0.5262 ppm, Cd 0.0212 ppm
3668 (N) Brown : Pb 0.2401 ppm, Cd 0.0055 ppm
3737 (N) Black : Pb 0.1469 ppm, Cd 0.0057 ppm
Covercoat Flux : Pb 0.2016 ppm, Cd 0.0037 ppm
* Covercoat Flux
We can obtain a transparent and glossy glaze surface by screen printing with the Covercoat
Flux on the base color printed such as Cd bearing, Normal colors, Pink, Purple
and Cobalt Blue colors.
This Cover Coating Flux is a special glass flux for a minimum Pb and Cd detection
effect after firing.
For reducing detecting rate of heavy metal, It is recommended to use our Covercoat Flux
with Cobalt Blue color and Cadmium color series of Onglaze colors which
content high level of heavy metal.
Example :
The submitted samples, When tested as described, comply with the leachable lead and
cadmium requirements of the American Food and Drug Administration (FDA) Compliance
policy Guides 7117.06 and 7117.07
Sample :
Covercoat Flux
No. 3181 Orange color ( 5 x 10 cm ) ---------- 1 dm2
No. 3589 Cobalt Blue color ( 5 x 10 cm )--------1 dm2
Leachable Lead and Cadmium Content
Flat ware, Internal surface
14 mm Depth 175ml Volume 2.05 mg/ml Lead 0.24 mg/ml Cadmium
Limit for FDA 3.0 mg/ml Lead 0.5 mg/ml Cadmium
* Regulaton on of tableware in California limits by commodity, by chemical
Ware :
Flat ware ( Internal Depth ( ?25 m/m ) : 3.0 ppm Lead, 0.50 ppm Cadmium
Small hollow ware ( Volume < 1.1 liter ) : 2.0 ppm Lead, 0.50 ppm Cadmium
Large hollow ware ( Volume ? 1.1 liter ) : 1.0 ppm Lead,
0.25 ppm Cadmium
New cup. Mug (Standard): 0.5 ppm Lead, 0.50 ppm Cadmium
New pitcher ( Volume ? 1.1 liter ) Standard : 0.5 ppm Lead, 0.25 ppm Cadmium
New FDA action levels.
CPG7117.07, CPG 7117.06, ' Action Levels of Nov. 5, 1991
* 3000 Series Color List
COLOR NO. / COLOR / C = Cadmium, N = Normal: REMARK
0360 Pink (SF01) (Gold & N) : Produce Purple color, mixed /diluted with 3589 Cobalt Blue
3149 Pink Red (N) : Widely using as Gold free Pink color
3127 Cd Red (C) : The firing temperature range is wide as 800 ~ 850 C' and usable to fast firing (850 ~ 950 C') too.
Therefore, 3127 color's inner heat-resistant and gas-resistant is high.
3151 Red (C) : Using deeper Red color than No.3127 Red, for dipping color.
3155 Dark Red (C) : Same as above
3181 Orange (C)
3182 Orange (C)
3232 Light Yellow (N)
3241 Yellow (C)
3243 N - Yellow (N)
3244 Golden Yellow (C)
3245 Pumpkin Yellow (N)
3313 Mixing White (Cd Line) (C & N) : this color is using as mixing Cd color class. It is almost no change of color tone.
3366 Mixing White (N) : This color is mixable with other normal color class.
3320 - 1 Opaque White (N) : This color is using by only single color. Opalescent effecting is very high, but 3320-1 is greenish in case of folding with Cobalt Blue. In addition, this color is Yellowish on the edge folded with Black color.
3326 Opaque White (N) : This color is new product making up for the weak points in 3320-1 and has the strong points as the followings; White opacity, masking powder, Gloss is good. Using Covercoat Flux, the gloss is better. However, the opacity of 3326 is weaker than 3320-1. This color does not change to Yellow tone even high temperature. Therefore, this color does not change to Green tone in case the coating is Cobalt Blue class. It is nothing to worry about color change even with any Cd class color. Especially,this color not be contaminated by low temperature Black color.
3315 Relief White (N) : Because the coefficient of expansion is low, this color is not the phenonmenon of peeling off. in addition, the White opacity and the gloss are good. This color can control the gloss and the transparency by mixing with Relief Flux 3015
3412 Ever Green (N)
3425 Yellow Green (C) : If you want to get more bright color, we recommend diluting as mixing with 3244.
3470 Teal Green (N)
3471 Grass Green (N)
3490 Olive Green (N)
3491 Olive Green (N)
3493 Green (N)
3536 Turquoise Blue (N)
3537 Turquoise Blue (N)
3547 Blue (N) : This color is a transparent and bright color. It is easy to mix with other colors. 3547 Blue color is no changing color by Covercoat Flux.
3562 Purple Blue (GOLD & N) : Purple Blue color bearing gold.
3589 Cobalt Blue (N) : The strength of No.3589 is a strong color. In additions, this color has no change color by the Covercoat Flux and no decolorization on the high temperature. Just, This color has a weakness unable to mix with other colors. Therefore, If possible, you had better mixing within 4% otherwise, you should pre-test it.
3590 Cyan Blue (N) : Usable for 4 color
3591 Green Blue (N)
3620 Choco. Brown (N) : Carefully use Covercoat Flux with this color to avoid color change
3656 Light Brown (N)
3669 Brown (N)
3670 Red Brown (N)
3737 Black (N) : Recommend to use alone or mixing with other color
3745 Black (SF77) (N) : Strong Black color and can be used alone without mixing with other color, Specially used
for 4 color
3783 Grey (N)
Covercoat Flux (N) : Because 3000 series contains a little heavy metal, the importance of coating flux grows bigger. This Covercoat Flux minimizes the detection rate of heavy metal ( Pls. see KOTITI FDA testing report). Without changing color, This Covercoat Flux improves gloss (-Except Iron Red, Choco. Brown color). Over the strong Reddish Gold Pink and on the low temperature. this color is Brownish.
4 Color SF01, SF25, SF 58 & SF 77 (N) :Recommend 4 base colors Pink (SF01), Yellow (SF25), Cyan Blue (SF58) and Black (SF77), those are a little different color tone from other intrenational grade so need pre-testing before use it.
This is none pollution colors free from Cadmium/Lead and acceptable environmental-issue but the firing range is about 30? higher (800~860?) than lead bearing onglaze color 3000 series.
Therefore, It is recommended to use lead free Covercoat Flux for reducing the firing temperature.
* Pb and Cd Free Color
6000 Series contain normal Cd free color which have wide range of the firing temperature to get stable color tone. Can be mixed with other colors. As the mixing rates, you can get your wanted color match.
* Application
6000 Series do not contain heavy metals and any health organizations do not issue the problem of heavy metals. However, comparing with 300 Series, th firing temperature is 30? higher (800~860?). Therefore, 6000 Series need 6955 Covercoat Flux for improving the gloss. 6000 Series normally is used to the using method of printing it on the decal paper, then sticking it to the materials, and firing it. However,It is possible to use as dipping, spraying and hand painting method.
* Mixing Ratio Between Dry powder and Medium Oil
Normal Color 10 vs. Medium Oil 7 ~ 10
Normal color 10 vs. Covercoat Flux 9 ~ 10
* 6000 Series Color List
COLOR NO. / COLOR / C = Cadmium, N = Normal: REMARK
0660 Red Pink (GOLD) : Regarding to 6955 Covercoat Flux, the color change is small. (It is Brownish from 760C' to 780C' by covercoat flux) By mixing 6313 mixing White or
6149 Pink Red (N), bright rose comes out. By mixing 6588 Co.Blue, any violet color comes out.
6140 Iron Red (N) : It is impossible to mix with other colors.
6149 Pink Red (N) : By normal Pink-color class, the using range is wide. In addition, If applying Skin-color, the result comes out good.
6231 Light Yellow (N) : By bright normal Yellow class, the using range is wide.
6245 Pumpkin Yellow (N) : The firing stability is high. It is mixable with other normal color class.
6313 Mixing White (N) : It is mixable with other colors and minimizes the changing color.
6326 Oq. White (N) : White chroma, hiding, Gloss is good. Using 6955 covercoat flux, the gloss is better. This color does not change to Yellow tone even high temperature. Therefore, this color does not change to Green tone in case the cover coating is Cobalt Blue class. It is nothing to worry about color change even with any Cd class color. Especially, this color not be contaminated by low temperature Black color.
6315 Relief White (N) : Because the coefficient of expansion is low, this color is not the phenomenon of peeling off. In additions, the White Chroma and the gloss are good. This color can control the gloss and the transparency by mixing with Relief Flux 6015. All 6000 Series colors are usable as relief color by mixing over 50% relief- mixing fluxes. 6000 Series C.T.E : 67-73x10-7/?
6471 Grass Green (N) : It is the transparent relief flux improving transparency.
6412, 6476, 6470, 6486, 6485 Green color (N) : These colors carrying a strong resistant are no change colors by the firing conditions and the coating flux.
6536, 6537 Turquoise Blue (N) : When firing them on the high temperature above 850?, they change to Green color tone. However, 6955 covercoat flux makes up for the fault.
6547 Blue (N) : This color is transparent and bright color. It is easy to mix with other color.
6588 Co-Blue (N) : The strength of No.6588 is that the color is strong and bright. Just, it is not easy to mix with other colors.
6620 Choco Brown (N) : If using the oxidized steel included in pigment, the color become bright.
6669 Brown (N)
6670 Red Brown (N)
6737 Mixing Black (N) : this color is easy to mix with other colors and is a stable color.
6955, 6966 Covercoat Flux (N) : 6000 Series are 30? higher than 3000 Series. By using 6955 covercoat flux, the gloss improves and 6000 Series are getable to the effect of lowing the firing temperature. Excepting to 6140 Iron Red, 6620 Choco Brown color 6955 improves the gloss without changing color.
* Result of Chemical Resistance Test
(Surface area : 1dm2, depth 13 mm, volume : 70 ml, Flatware)
ex.number / color / Pb(ppm) / Cd(ppm)
0660 Red Pink (GOLD) Pb 0.03 ppm, Cd Les than 0.01 ppm
6140 Iron Red Pb 0.03 ppm, Cd Les than 0.01 ppm
6149 Pink Red Pb 0.05 ppm, Cd Les than 0.01 ppm
6245 Pumpkin Yellow Pb 0.08 ppm, Cd Les than 0.01 ppm
6313 Mixing White Pb 0.03 ppm, Cd Les than 0.01 ppm
6471 Grass Green Pb 0.02 ppm, Cd Les than 0.01 ppm
6537 Turquoise Blue Pb 0.04 ppm, Cd Les than 0.01 ppm
6588 Cobalt Blue Pb 0.05 ppm, Cd Les than 0.01 ppm
6670 Red Brown Pb 0.05 ppm, Cd Les than 0.01 ppm
6737 Black Pb 0.01 ppm, Cd Les than 0.01 ppm
3. 3000 Series Color Used To Dinnerware.
3000 series color of cleaning is required therefore it must check alkari resistance in cleaning
solution against mechanical durability such as friction and lower wearing. So 3000 series colors
are manufactured to than datum point of heavy metal detection.
The datum point is distinguished by detection of each nation as following
1) Part contract with food
Country-----------Metals------------------Acid-----------------Temp.--------Time(Hrs)--------Limited and Notes
Switzerland-------Pb, Cd, Zn----------------4% Acetic------------Room----------24------------------- 3mg/dm2
Norway-----------Pb, Cd, Sb, Zn------------4% Acetic------------Room----------24------------------- 0.6mg/dm2
Germany----------Pb--------------------------4% Acetic------------Room----------24------------------- 1.5mg/dm2
Italy----------------Pb--------------------------4% Acetic--------------Room----------24------------------- 0.5mg/dm2
2) Quality of heavy metal within dinnerware.
Country-----------Metals-----------Acid--------------Temp.-------Time(hrs)---Limited and Notes
Canada------------Pb, Cd-----------4% Acetic-------Room--------18-------------Pb:7ppm, Cd:0.5ppm
Britain-------------Pb, Cd-----------4% Acetic-------Room--------24--------Ware:(<1.1L) Pb:7ppm Cd:0,2ppm
------------------------------------------------------------------------------------------------Ware:(>1.1L) Pb:2ppm Cd:0.2ppm
Australia----------Pb, Cd----------4% Acetic------19~21'C--24--Ceramicware:(>1.1L)Pb:20ppm Cd:2ppm
--------------------------------------------------------------------------Small Hollow ware:(<1.1L)Pb:7ppm Cd:0.7ppm
U.S.A.(FDA)------Pb, Cd------------4% Acetic-------Room--------24-------------Pb:7ppm Cd: 0.5ppm
India-------------------Pb------------5% Acetic-------Boil-----------1/2------------2ppm
Sweden------------Pb--------------4% Acetic-------Boil------------3+1/2--------3ppm
Japan---------------Pb, Cd---------4% Acetic-------Room---------24----------Flat ware: Pb:20ppm Cd:0.5ppm
--------------------------------------------------------------------------Hollow ware: (<1.1L) Pb:7ppm Cd:0.5ppm
Korea---------------Pb, Cd---------4% Acetic-------Room---------24-------------Pb: 7ppm Cd: 0.5ppm
3) Result testing by detection method : 3000 Series Colors : dm2 - Testing by KSL1204 (192)
No-------Color------------------------Pb:ppm/dm2-----------------Cd:ppm/dm2
3150----Red (C)-----------------------0.84-------------------------------0.63
3149----Pink Red (N)----------------0.37----------------------------------
3232----Yellow (N)-------------------0.84--------------------------------0.18
3244----Yellow (C)-------------------0.75--------------------------------0.08
3366----Mixing White (N)----------0.32--------------------------------0.08
3378----Mixing White (C&N)-----0.50--------------------------------0.06
3415----Green (N)--------------------0.10--------------------------------0.07
3470----Green (N)--------------------0.16--------------------------------0.05
3537----Turquoise Blue (N)-------0.34--------------------------------0.05
3589----Cobalt Blue (N)------------1.50--------------------------------0.04
3745----Black (N)---------------------0.27-------------------------------0.08
3977----Flux (C&N)------------------0.05-------------------------------0.02
4) FDA checked to dinnerware by function of application ceramicware and restriction quantity
to FDA is as following:
Category----Specification---* CPG lead level (Micro G/ML)------* CPG cadmium level(Micro G/ML)
Flatware-----Internal Depth<25mm---------3.0-----------------------------0.50
Small Hollowware--Volume<1.1L----------2.0-----------------------------0.50
Large Hollowware--Volume>1.1L----------1.0-----------------------------0.25
Cups & Mug------------------------------------0.5-----------------------------0.50
Pitchers----------------Volume<1.1L----------0.5-----------------------------0.50
Pitchers--------------------Volume>1.1L-------0.5-----------------------------0.25
Rin Test-------------Depth 20mm from rim--50----------------------------3.5
* CPG = Compliance Policy Guideline
Compare with other company and our company, our company have a few detection quantity
but according to color number seem to difference.
Reference metal (Pb, Cd) of detection testing is as following. Partially immerse annealed sample
of decorated ware in 4% Acetic Acid Solution for 24 hours. Acetic Acid Solution of component
test doing to Automatic Absorption spectroscoy or ICP spectrometry, and that it sign to mg,ppm
to Pb, Cd detection quantity. Hollowware have a far than about 25mm deep,Flat ware is smallest
than hollowware 1.1L
Screening Pastes
General Description
Screen pastes consist of mixture of fusible vitreous fluxes and inorganic pigments, combined
in an organic medium to from a paste, suitable for application to porcelain enamelled surfaces
by silk screening. After silk screening, the pastes are dried, then fired at temperature 20~50 deg.C
lower than the temperature at which the enamelled substrate was fired. The fired screening color
fuses to the enamelled substrate to from a durable, heat and solvent resistant coloured pattern.
If preferred, screening colors can be supplied as powders, so that customers may mix them with
their own preferred mediums for printing Decals where overprint (Transfer ) lacquers are used,
and if kept dry, powder have indefinite shelf life.
1. Preperation of Screening paste for printing
Supplies pastes at a viscosity which is generally higher than that required for screening.
The high viscosity is desirable during manufacture, to aid dispersion of pigments, and is
desirable in storage to minimize settling of pigments and fluxes. The only preparation required
before use is to thoroughtly stirring the pastes and to making them to the required viscosity
for screening.
After stirring, a quantity of paste, sufficient for say one operating shift, should be removed from
the bulk container. The bulk container should be ersealed and stored away from heat and
moisture. With proper storage, screening pastes will lasting for many years. The small quantity
of working paste may then be thinned for screening.
2. Thinning Oil, Squeegee Oil or Medium
The thinning oil (Squeegee Oil) or Medium to be used for thinning the pastes should be that
specified by the paste manufacturer. Most thinning oils are based on pine oil, and some pine oils
may even be used for thinning, However, there are many different grades of pine oil, and lower
grades may contain moisture or volatile solvents, which caused the paste to become thixotropic
or to dry rapidly on the screen. Pine oils may also reduce the effectiveness of resins and binders
in the medium and reduce bisque strength.
The medium for screening pastes usually contain flow control agents and resins which facilitate
the screening operation and allow the paste to dry to a smooth, tough 'bisque' which will be
scuff resistant. The medium also must burn away cleanly during firing, so as not to cause
blistering.
Only use the minimum amount of thinning medium to adjust paste to screening viscosity.
We manufacture several Mediums, those of which are suitable for use with enamel screening
pastes.
3. Application
Screens may be made from stainless steel, Nylon or Polyester : Polyester is generally the most
cost effective for general enamel screen printing and mesh sizes range from 43t (#110 per inch)
to 90t (#230 per inch) for most applications. The difinition and thickness of print determine the
mesh size used but for general printing, 61t~77t Polyester, with direct stencil, is commonly used.
The size of pattern to be printed and type of printing operation (Machine operation or Manual
squeegee), also help determine mesh size and type of screens to be used.
4. Specification for screening colors
Almost any colour obtainable in porcelain enamel is obtainable in screening colour and when
requesting a screening colour, the following conditions should be specified ;
(1) Colour
A. Supply either a colour chip of the colour required, or quote a Pantone or RAL colour number.
(Note that in the Pantone colour chart, there are two colours fo each colour number, viz, 'C'
for coated colour and 'U' for uncoated. The coated colour has higher gloss and is a slightly
different colour to the uncoated colour. Make sure that the correct colour and glossy are quoted. )
B. Specify the gloss level required as glossy, stain (semi gloss) or matte.
C. Specify the closeness of colour match required as exact, close or not critical. For very thin
lines, the colour match is not as critical as for larger print areas, so an indication of the print
design and dimensions may facilitate colour matching.
D. Specify the base colour on which the screen colour is to be applied. Light colours applied
over dark base colours will not cover as well as if applied over light colour, and the base colour
may change the appearance of the screen colour. Ideally, supply some small flat plates of the
fired base colour, so that the screen colour can be tested on the base colour at the time of
matching, thus ensured that the colour will be correct, the first time it is submitted for approval.
E. Indicate if one color is going to be printed over another.
(2) Type of body and firing temperature of screen color
A. Specify the type of base enamel and screening colour firing temperature to be used.
Sheet iron screening colours are fired at 750~800 deg.C
Screening colours on aluminium are fired at about 550 deg.C
As furnace behave differently, firing tempeatures actually used in production may differ from
those used during testing, so screening colour samples should always be tested under production
conditions before being accepted.
Rather than reduce furnace temperature for firing screen colours, it is often better to increase
furnace belt speed.
B. If there are other special requirements, such as chemical resistance, these should be tested for
when samples are submitted.
5. Printing environment and practice
The screen printing area should be free of dust and away from drag. Whilst not mandatory,
temperature and humidity control are desiratroy but are usually only justified when serious
processing or quality problems arise from extremes of temperature and high humidity.
If pastes are mixed with prescribed mediums in accordance with manufacturers instructions.
and are kept in sealed containers away from moisture, then printing problems should not arise.
After printing, screening pastes may be allowed to air dry, or that may be force dried with a
combination of forced air and heat.
Unused paste from the screen may be returned for later use, to the working paste container,
which should also be kept sealed to eliminate moisture and to prevent the paste from drying out.
Screens may be cleaned by wiping with a cloth and mineral turpe.
6. Safety and Handling
The fluxes and pigments used in screening pastes and powders may contain toxic elements such
as lead and cadmium. Those components are combined in a relatively insoluble form and
should not cause any hazard to persons using them, provided that normal standards of personal
hygiene are observed.
GLASS COLO
Acid Resistance Test
* Method :
Partially immerse annealed sample of
decorated ware in 10 Vol% HCL solution for 10 min.
Immersion in 2.5 Vol% H3PO4 for 24hrs
at room temperature. (22+ -2?)
* Result :
A - No visual effect.
B - Slight dulling of surface.
C - Extreme dulling of surface.
* Alkali Resistance Test
* Method :
Immerse in 10% mixed alkali solution (9% NaOH + 1% Na3PO4 12H2O + 90% H2O) at 88 + - 1 ?for 16 hours
( Coca-cola ACL Test)
Immerse in 10% mixed alkali solution ( 9.5% NaOH + 0.5% Na3PO4 12H2O + 90% H2O ) at 71 + - 1? for 24 hours
( Seven-up ACL Test)
* Only, thickness of printed glass color is 25~30 micron
* Result :
A - No gloss and keep opacity mostly
B - No gloss and weak opacity
C - No gloss and lost opacity mostly
* Sulfide Resistance
Preparation of reagents :
Sodium Sulfide (Na2S 9H2O )
Acetic Acid ( CH3COOH, min. 99.8% )
Dissolve an excess amount of sodium sulfide in warm (35 to 40 ?) distilled water. Make sure there is
undissolved sodium sulfide left over. Cool to room temperature.
Stir into each 100ml of the 4% acetic acid solution 1ml of saturated, clear, sodium sulfide solution for 2 or 3 min.
A milk of sulfur will be precipitated.
Place the test specimens and the reference standard of known resistance into the test solution
prepared according to the above at room temperature so that only half of the decoration is immersed.
Stir and cover.
Remove specimens from solution after 15 min and allow to air dry.
Note the degree of attack after 15 min by visual observation and grade.
* Result of Chemical Resistance Test
Series and ----------Acid -------------Alkaline -------Hydrogan Sulfide--Lithium content (ppm)
color-------------------Resistance----Resistance-----Resistance----------------------------------------
5000 Series----------A-----------------A--------------------A---------------6 ~ 10
7000 Series----------B-----------------B--------------------B---------------30 up
SR7000 Series-----C-----------------C--------------------C----------------30 up
8000 Series---------D------------------D--------------------D---------------30 up
4000 Series---------A------------------A--------------------A---------------6 ~ 10
? Maximum Lithium Content
Natural lithium content is minimized not exceeding 0.003% (30 ppm) for 5000 & 4000 series.
We have arranged the various series of numbering
such as
8000 ( 500~560?)
SR7000 ( 560~580?)
7000 ( 580~620?)
5000 ( 620~640?)
4000 ( 640~680?)
The first number 8, SR7, 7, 5, and 4 for the use of series number, the second number for the specific colors ie.
100 : Red Color
200 : Yellow Color
300 : White Color
400 : Green Color
500 : Blue Color
600 : Brown Color
700 : Black Color
The 3rd and 4th number for the specific color tones.
For example, No. 5105 ----------- Coca Red
First Number : 5 --------------------- Series number for the use
Second Number : 1----------------- Specific color
3rd and 4th Number : 05---------- Specific color tone
Glass Color List
Number---------------------- Colors
101 --------------------------- Red
102 --------------------------- Red Orange
105 --------------------------- Coca Red
107 --------------------------- Pepsi Red
110 --------------------------- Maroon
167 --------------------------- Orange
183 --------------------------- Pink
188 --------------------------- Pink
201 --------------------------- Yellow
202 --------------------------- Yellow
380 --------------------------- White
382 --------------------------- Matt White
395 --------------------------- Frost White
411 --------------------------- Light Green
422 --------------------------- Yellow Green
461 --------------------------- Green
463 --------------------------- Grass Green
468 --------------------------- Blue Green
469 --------------------------- Miranda Green
506 --------------------------- Turquoise Blue
512 --------------------------- Blue
517 --------------------------- Fanta Blue
521 --------------------------- Sky Blue
522 --------------------------- Pepsi Blue
528 --------------------------- Robin-egg Blue
534 --------------------------- Blue
536 --------------------------- Turquoise Blue
548 --------------------------- Cobalt Blue
550 --------------------------- Blue
620 --------------------------- Choco Brown
639 --------------------------- Light Brown
649 --------------------------- Brown
701 --------------------------- Black
FL-70S ---------------------- Clear Flux ( 560~600? )
M-0039 ---------------------- Metallic Gold ( 640~700? )
M-4001 ---------------------- Metallic Silver ( 640~700? )
6850 ------------------------- Squeegee Oil
6500 ------------------------- Squeegee Oil
6802 ------------------------- Medium ( Water Base )
3840 ------------------------- Decal Screen Oil
3860 ------------------------- Decal Coating Oil
3800 ------------------------- Decal Cleaner Oil
* 8000 Series Glass Color for Tableware
Powder Type
Number & Color
8101 Red
8110 Maroon
8102 Red Orange
8167 Orange
8188 Pink
8201 Golden Yellow
8202 Yellow
8380 White
8382 Matt White
8411 Light Green
8468 Blue Green
8461 Green
8463 Grass Green
8422 Yellow Green
8506 Turquoise Blue
8536 Turquoise Blue
8548 Cobalt Blue
8550 Blue
8512 Blue
8534 Blue
8521 Sky Blue
8528 Robinegg Blue
8620 Choco Brown
8649 Brown
8639 Light Brown
8701 Black
8071 Gold Pink
Packing : 5 kg in plastic container, or 50 kg Can.
* SR 7000 Series Glass Color for Tableware
Thermoplastic Type
Number and Color
7101 Red
7110 Maroon
7102 Red Orange
7167 Orange
7188 Pink
7201 Golden Yellow
7202 Yellow
7380 White
7382 Matt White
7411 Light Green
7468 Blue Green
7461 Green
7463 Grass Green
7422 Yellow Green
7506 Turquoise Blue
7536 Turquiise Blue
7548 Cobalt Blue
7550 Blue
7512 Blue
7534 Blue
7521 Sky Blue
7528 Robinegg Blue
7620 Choco Brown
7649 Brown
7639 Light Brown
7701 Black
7071 Gold Pink
Packing : 50 kg Can
* 7000 Series Glass Color for Dinnerware & Tumblers
Powder Type
Number & Color
7000 Flux
7072 Purple
7101 Red
7102 Red Orange
7105 Light Red
7125 Red Orange
7188 Pink
7201 Golden Yellow
7202 Yellow
7380 White
7422 Yellow Green
7463 Grass Green
7464 Green
7468 Blue Green
7482 Green
7506 Turquoise Blue
7526 Blue
7534 Blue
7536 Turquoise Blue
7548 Cobalt Blue
7565 Blue
7620 Choco Brown
7639 Light Brown
7670 Brown
7701 Black
Packing : 5 kg in a plastic container,
* 5000 Series Glass Color for Bottles ( Coca Etc...)
Powder Type
Number & Color
5105 Coca Red
5107 Pepsi Red
5380 White
5469 Miranda Green
5522 Pepsi Blue
5517 Fanta Blue
Packing : 5 kg in a plastic container, or 50 kg Can.
The hot colors consisted of thermoplastic medium that is starting to melt at 70~80? and print it on cold ubstances. It is special notice that the melting temperature must be not over decompose temperature 100? that causes of unacceptable printing results in colors. Prepare liquid form of paste color after heated app. 75 ? and start to print. The material of screens is recommended stainless steel and heat by D.C. electric currency.
The followings are advantages and disadvantages of hot color application.
* Advantage
1) High efficiency for multicolor printings.
2) Fine printing parts available.
3) Continuous in round part of printings are available.
4) Increase of printing speed and productivity.
5) Less content of volatile materials so it is easy to clean up blinding part of screen mesh.
* Disadvantages
1) Required electrical resistant heating element.
2) Complicate work to change screens.
3) Less life cycle of screens.
4) Must use hot water for repairing printing part.
The thinning oil or Medium to be used for thinning the
pastes should be that specified by the paste manufacturer.
Most thinning oils are based on pine oil, and some pine
oil may even be used for thinning, however there are
many different grades of pine oil, and lower grades may
contain moisture or volatile solvents. Which caused the
paste to become thixotropic or to dry rapidly on the
screen. Pine oils may also reduce bisque strength.
The medium for screening pastes usually contains flow
control agents and resins which facilitate the screening
operation and allow the paste to dry to a smooth,
tough ' bisque ' which will be scuff resistant.
The medium also must burn away clearly during firing,
so as not to cause blistering.
Only use the minimum amount of thinning medium to adjust paste to screening viscosity.
Component
* Component of Glass Color :
Glass color is consists of Frit powder and Inorganic color stain. Properties of Glass color is
determined by Frit. So. Frit is division to contained lead and lead free frit. :
(1) Component limit of frit
SiO2-------------------35 ~ 40 wt%
ZrO2---------------------5 ~ 10 wt%
B2O3 ------------------ 3 ~ 7 wt%
PbO ------------------- 30 ~ 35 wt%
TiO2 --------------------5 ~ 15 wt%
R2O --------------------3 ~ 5 wt%
Etc....-------------------5 ~ 8wt%
(2) Component of Inorganic pigment
1) Red stain ----------------------CdSe, CdS, ZnS, BaSO4
2) Yellow stain ----------------- CdS, sb2O3, TiO2
3) White stain ------------------- TiO2, SnO2
4) Green stain ------------------ Cr2O3, CoO, ZnO, NiO
5) Blue stain --------------------- CoO, Al2O3, ZnO
6) Brown stain ------------------- Fe2O3, ZnO, Cr2O3
7) Black stain -------------------- MnO2, Cr2O3, CuO, Fe2O3, Nio
* Squeegee Oil Screen Oil :
Squeegee oil consists of main component that is pine oil. Pine oil can controll dry speed at
a volutile solvent. The others contained a jointner, a hardener and a moisturer.
* Hot color of Thermoplastic color :
Hot color consists of main component that is Stearyl Alcohol and Cetyl Alcohol as solid alcohol.
The others contained a ignition, a plasticizer and moisturer.
Wax component of hot color is about 18 wt%
Using Method and Manufacture of Glass Color
Glass color have to following manufacture according to using method
* Paste Type Color
To low-melt point glass frit powder include to inorganic color stain and maked paste type mixing
with squeegee oil paste colors are manufactured by mechanization triple roller and at time it
dough condition use mixing suitable with squeegee oil.
* Thermoplastic Type Color or Hot Color
Thermoplastic color is solid state on the normal temperature mixing maked melt to wax instead
of squeegee oil. It becomes at once solid on printing to paste condition heating at 70~80'C
temperature. Therefore, first print case is need not to dry. Accordingly, It is suit to precision more
print and many auto production.
* Dry Powder Type Color
Case on the powder from it is easy to application according to useing purpose. For example,
spray time by spraygun to squeegee oil and solvent or terepin oil, and print on transfer paper
etc..., powder from convenience receive to it.
A average particle size distribution of glass color is about 2.5 Micro M.
* Squeegee Oil or Screen Oil
Squeegee oil is easy to volatile combustibility refer to softening temperation of glass color and
firing speed. It was control as combine to print efficiency, cover of lengthen, thickness and design
of ingredient. Paste from included squeegee oil About 20% but it is difference by supplies.
Screen oils are classify to many kind of oil according to relative utensil or print method.
* Crinkle Color
Assembler condition of crinkle was division transparent crinkle and color crinkle also temperature
range have difference according to dishes. This crinkle requires to notice on presentation
standard temperature and it's application to peculiar design.
Trouble - Shootings of Hot Color
Trouble - Shootings of Hot Color
* Peeling off as printing
The part of Hot Color sometimes peels off from glass substrate after the first color printing during
the second color printing. The problem can be remedied by taking care of the following points:
1) Do not enforce on squeegee rubber in printing process.
2) Do not heat up rapidly on the surface of wares.
3) Remove oil and moisture from the surface of wares.
* Moire
As for glass color, it is advantageous to have a certain film thickness for the uniform color tone
and chemical resistance (especially alkaline resistance). With respect to the color tone, the color
with weak covering powder such as Blue color, can not give a normal color tone and a uniform
color if the film thickness is not enough. In general, the thickness is required to have 20~30
Micro M as the first color (Usually White). The adjustment of thickness is available to lower the
temperatures of the glass substrate and of a screen as far as it keeps enough surface leveling.
The moire effect sometimes occurs on the second color. However, this problem can be solved
by keeping a good surface leveling on the color and/ or using 200 mesh screen for the first
color and mesh screen for the second color.
* Running of Sag
Running occurs in a range of 100~200'C in a lehr. Running inhibiting method are shown as
follows ;
1) The temperature and time which the wax in Hot Color decomposes and vaporizes rapidly
and sufficiently should be given in a preheating zone. This running is apt to accur especialy
when the glass ware is big or the number of glass wares in a lehr is increased.
2) Sufficient ventilation in a lehr in preheating zone should be done in order to promote
decomposing and vaporizing of wax component.
3) The glass ware should be put at a wider interval in a lehr.
4) In a lehr the glass wares should not be placed opposite printed surface, each other.
* Blistering
Blistering is the phenomenon that the organic compounds in glass color do not decompose and
not vaporize rapidly, and remain till reaching a melting point of frit, and then evaporate as a
viscosity of frit decreasing. At this time, the layer of glass color is blistered like a sponge.
Therefore, this trouble relates to the temperature control and the ventilation in the preheating
zone. Blistering is also solved by the same remedies as in the running case.
Rarely, blistering occurs in high temperature zone when the wax in the color is carbonized by
bringing the printed surfaces into direct contact with flames of fuel in a lehr and remains in the
frit.
eling off as printing
The part of Hot Color sometimes peels off from glass substrate after the first color printing during
the second color printing. The problem can be remedied by taking care of the following points:
1) Do not enforce on squeegee rubber in printing process.
2) Do not heat up rapidly on the surface of wares.
3) Remove oil and moisture from the surface of wares.
* Moire
As for glass color, it is advantageous to have a certain film thickness for the uniform color tone
and chemical resistance (especially alkaline resistance). With respect to the color tone, the color
with weak covering powder such as Blue color, can not give a normal color tone and a uniform
color if the film thickness is not enough. In general, the thickness is required to have 20~30
Micro M as the first color (Usually White). The adjustment of thickness is available to lower the
temperatures of the glass substrate and of a screen as far as it keeps enough surface leveling.
The moire effect sometimes occurs on the second color. However, this problem can be solved
by keeping a good surface leveling on the color and/ or using 200 mesh screen for the first
color and mesh screen for the second color.
* Running of Sag
Running occurs in a range of 100~200'C in a lehr. Running inhibiting method are shown as
follows ;
1) The temperature and time which the wax in Hot Color decomposes and vaporizes rapidly
and sufficiently should be given in a preheating zone. This running is apt to accur especialy
when the glass ware is big or the number of glass wares in a lehr is increased.
2) Sufficient ventilation in a lehr in preheating zone should be done in order to promote
decomposing and vaporizing of wax component.
3) The glass ware should be put at a wider interval in a lehr.
4) In a lehr the glass wares should not be placed opposite printed surface, each other.
* Blistering
Blistering is the phenomenon that the organic compounds in glass color do not decompose and
not vaporize rapidly, and remain till reaching a melting point of frit, and then evaporate as a
viscosity of frit decreasing. At this time, the layer of glass color is blistered like a sponge.
Therefore, this trouble relates to the temperature control and the ventilation in the preheating
zone. Blistering is also solved by the same remedies as in the running case.
Rarely, blistering occurs in high temperature zone when the wax in the color is carbonized by
bringing the printed surfaces into direct contact with flames of fuel in a lehr and remains in the
frit.
COLD DECAL PRINTING INKS
MATERIAL SAFETY DATA SHEET ( DATA PREPARED : 1996.9.10 )
======================================================
BRAND : STARPOL BK-3000 SERIES
-----------------------------------------------------------------------------------------------------------------
1.COMPOSITION / INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------------------------------------------
COMMON NAME------CAS No.-------CLEAR (%)-----COLORED (%)
Epoxy Resin -----CAS No. 25036-25-3-----Clear 25~35%-----Colored 60~95%
Poly Urethan Resin----Clear 15~25%-----Colored 60~95%
Aromatic Solvent Naphtha-----CAS No.64742-95-6-----Clear 15~25%-----Colored 60~95%
Methyl Methoxy Butanol-----CAS No.56539-66-3-----Clear 5~10%-----Colored 60~95%
EB Acetat-----CAS No.112-07-02-----Clear 20~30%-----Colored 60~95%
Pigments ( colored products )---------------------------------Colored 5~40%
The manufacturers reserve the right to alter and improve the specifications without notice.
------------------------------------------------------------------------------------------------------------------
2.HAZARDS IDENTIFICATION
------------------------------------------------------------------------------------------------------------------
INHALATION :
EYE CONTACT : Irritating to eyes
SKIN CONTACT: Irritating to skin
-----------------------------------------------------------------------------------------------------------------
3.FIRST AID MEASURES
-----------------------------------------------------------------------------------------------------------------
3.1 General Remarks :
Bring affective person out of danger area.
Place person on side instable position if unconscious.
Employ mouth-to-mouth resuscitation if breathing ceases.
3.2 Inhalation :
Bring affective person outside and ensure that he/she is comfortable.
Employ mouth-to-mouth resuscitation if breathing ceases.
3.3 Skin contact
On skin contact, rinse thoroughly with water.
With continous skin irritation, consult doctor.
3.4 Eye contact :
Rinse thoroughtly immediately for at least 5 minutes keeping eyelid open,
Further treatment by eye doctor.
3.5 Ingestion :
Supply with medical care.
------------------------------------------------------------------------------------------------------------------
4.FIRE-FIGHTING MEASURES
------------------------------------------------------------------------------------------------------------------
4.1 Suitable extinguishing media :
Usual measures for chemical fires.
4.2 Extinguishing media which must be used for safety reasons.
4.3 Special exposure hazards arising from the substance or preparation itself,
combustion products, resulting gases :
Formation of flammable or explosive vapour / air mixtures possible.
Danger of explosion with fire. Do not inhale explosive gases or smoke fumes.
4.5 Special protective equipment for fire fighters :
--------------------------------------------------------------------------------------------------------------------
5.ACCIDENTAL RELEASE MEASURES
---------------------------------------------------------------------------------------------------------------------
5.1 Personal precautions :
Keep persons at a distance and stay on them weather side.
5.2 Environmental precautions :
Dispose of waste in accordence with the legal regulations
issued by the appropriate local and national authorities
5.3 Methods of cleaning up :
Absorb with liquid-binding material (eg., sand, infusorial earth, inert absorbent).
5.4 Further information :
Remove all sorces of ignition.
------------------------------------------------------------------------------------------------------------------
6. HANDLING AND STORAGE
------------------------------------------------------------------------------------------------------------------
6.1 Handling :
No dangerous reactions are known to occur with correct handling and storage.
The product should only be handling by trained personnel.
6.2 Storage :
Fumes may be released in closed storage rooms or during processing.
Keep containes dry and tightly sealed-even empties.
The product is water dangering.
------------------------------------------------------------------------------------------------------------------
7. EXPOSURE CONTROLS / PERSONAL PROTECTION
------------------------------------------------------------------------------------------------------------------
7.1 Additional instructions for technical installation.
Eventual aspiration in case of solvent fumes. Technical protection
measures have always priority over personal protection equipment.
7.2 Ingredients with threshold limit values :
Values of maximum admissible concentration :
500 ppm referring to Solvents Naphtha, Aromat
7.3 Personal Protection
7.3.1. General Protection
Wash face / hands before break and of work.
7.3.2. Respiratory Protection :
If maximum admissible concentration value at the workplace is
exceeded or you feel trouble, apply respirator which charchol filter.
7.3.3. Eye Protection :
Wear safety goggles with side-shields (if handling large amounts).
7.3.4. Skin Protection :
Preventive skin protection recommended.
7.3.5. Hand Protection :
Wear protetive glove made of solvent-resistent material
(If handling large amounts).
-------------------------------------------------------------------------------------------------------------------
8. PHYSICAL AND CHEMICAL PROPERTIES
-------------------------------------------------------------------------------------------------------------------
8. Physical and Chemical Properties
8.1 Appearance
8.1.1 Physical State : Fluid
8.1.2 Colour : COLOURLESS or Characteristic
8.1.3 Odour : Characteristic
8.2 Data relevant to safety
8.2.1 Viscosity : ( 25'C) -> 12~25 Storkes
8.2.2 Flash Point : 64'C ( Closed cup )
8.2.3 Lower Explosion Limits : 0.6 Vol. - %
8.2.4 Upper Explosion Limits : 11.2 Vol. - %
------------------------------------------------------------------------------------------------------------------
9. STABILITY AND REACTIVITY
-------------------------------------------------------------------------------------------------------------------
9.1 Conditions to avoid :
When heated above flash point and / or with spraying or atomization,
a flammable mixture may form with air.
9.2 Materials to avoid :
(If applicable, information referring to individual components of the product
is given below ).
9.3 Hazardous decomposition products :
The product is supplied in a stable form, but if container left open at room
temperature or above, it will lose solvents by evaporation.
9.4 Further information
-------------------------------------------------------------------------------------------------------------------
10. TRANSPORT INFORMATION
-------------------------------------------------------------------------------------------------------------------
Dangerous goods regulations
RID/ADR/IMDG-Code/ICAO-TL
10.1 Land transport ADR/RID
(interstate / intrastate)
Not restricted.
10.2 Inland navigation ADN
For inland navigation consulation necessary :
10.3 Sea Transport IMDG
IMDG : Class 9 UN-No. 3062 PG III
Marine Pollutant : Yes
EMS : ---- MFAG : ----
Technical name reger to UN-No. :
Enviromentally hazardous substance, liquid, n.o.s. *
Hazardous substance :
Aromatic Solvents Naphtha, MMB, EB Acetat..
10.4 Air transport ICAO-YI and IATA-DGR
Not restricted
------------------------------------------------------------------------------------------------------------------
11. REGULATORY INFORMATION
------------------------------------------------------------------------------------------------------------------
Fallow all reguration in your country.
------------------------------------------------------------------------------------------------------------------
12. OTHER INFORMATION
------------------------------------------------------------------------------------------------------------------
Reference :
Kocosol #150 MSDS. SK Corp.
Methyl Methoxy Butanol MSDS. KURARAY CO.,LTD.
EPO-THOTO MSDS KUK DO CHEMICAL IND, CO. LTD.
MATERIAL SAFETY DATA SHEET ( DATA PREPARED : 1996.9.10 )
======================================================
BRAND : STARPOL BK-3800
------------------------------------------------------------------------------------------------------------------
1.COMPOSITION / INFORMATION ON INGREDIENTS
------------------------------------------------------------------------------------------------------------------
Common Name------------------CAS-No.---------------------%
Aromatic Solvent Naphtha -----CAS- No. 64742-95-6-----0~20 %
Methyl Methoxy Butanol ------- CAS- No.56539-66-3 -----50~70%
EB Acetat------------------------------CAS- No.112-07-02 ------30~50%
The manufacturers reserve the right to alter and improve the specifications without notice.
------------------------------------------------------------------------------------------------------------------
2. HAZARDS IDENTIFICATION
------------------------------------------------------------------------------------------------------------------
INHALATION :
EYE CONTACT : Irritating to eyes
SKIN CONTACT : Irritating to skin
------------------------------------------------------------------------------------------------------------------
3. FIRST AID MEASURES
------------------------------------------------------------------------------------------------------------------
3.1 General Remarks :
Bring affected person our of danger area.
Place person on side instable position if unconscious.
Employ mouth to mouth resuscitation if breathing ceases.
3.2 Inhalation :
Bring affected person outside and ensure that he/ she is comfortable.
Employ mouth to mouth resuscitation if breathing ceases.
3.3 Skin Contact
On skin contact, rinse thoroughly with water.
With continous skin irritation, consult doctor.
3.4 Eye Contact :
Rinse thoroughtly immediately for at least 5 minutes keeping
eyelid open, Further treatment by eye doctor.
3.5 Ingestion
Supply with medical care.
-----------------------------------------------------------------------------------------------------------------
4. FIRE-FIGHTING MEASURES
-----------------------------------------------------------------------------------------------------------------
4.1 Suitable extinguishing media :
Usual measures for chemical fires.
4.2 Extinguishing media which must be used for safety reasons.
4.3 Special exposure hazards arising from the substance or preparation itself,
combustion products, resulting gases : Formation of flammable or explosive
vapour / air mixtures possible. Danger of explosion with fire.
Do not inhale explosive gases or smoke fumes.
4.4 Special protective equipment for fire fighters :
------------------------------------------------------------------------------------------------------------------
5. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------------------------------------------------------------
5.1 Personal precautions :
Keep person at a distance and stay on them weather side.
5.2 Environmental precautions :
Dispose of waste in accordence with the legal regulations
issued by the appropriate local and national authorities
5.3 Methods of cleaning up :
Absorb with liquid-binding material (eg., sand. infusorial earth,
insert absorbent ).
5.4 Further information :
Remove all sorces of ignition.
-----------------------------------------------------------------------------------------------------------------
6. HANDLING AND STORAGE
-----------------------------------------------------------------------------------------------------------------
6.1 Handling :
No dangerous reactions are known to occur with correct handling and storage.
The product should only be handling by trained personnel.
6.2 Storage :
Fumes may be released in closed storage rooms or during processing,
Keep containes dry and tightly sealed-even empties.
The product is water dangering.
------------------------------------------------------------------------------------------------------------------
7. EXPOSURE CONTROLS / PERSONAL PROTECTION
------------------------------------------------------------------------------------------------------------------
7.1 Additional instructions for technical installation.
Eventual aspiration in case of solvent fumes. Technical protection
measures have always priority over personal protection equipment.
7.2 Ingredients with threshold limited values :
Values of maximum admissible concentration :
500 ppm referring to Solvents Naphtha, Aromat
7.3 Personal Protection
7.3.1 General Protection :
Wash face / hands before break and of work.
7.3.2 Respiratory Protection :
If maximum admissible concentration value at the workplace is exceeded
or you feel trouble, apply respirator which charchol filter.
7.3.3 Eye Protection :
Wear safety goggles with side-shields ( if handling large amounts).
7.3.4 Skin Protection :
Preventive skin protection recommended.
7.3.5 Hand Protection :
Wear protective glove made of solvent-resistent material (if handling large amounts)
-------------------------------------------------------------------------------------------------------------------
8. PHYSICAL AND CHEMICAL PROPERTIES
-------------------------------------------------------------------------------------------------------------------
8. Physical and chemical properties
8.1 Appearance
8.1.1 Physical state : Fluid
8.1.2 Colour : COLOURLESS or Characteristic
8.1.3 Odour : Characteristic
8.2 Date relevant to safety
8.2.1 Viscosity : ( 25 'C ) -> 12~25 Storkes
8.2.2 Flash Point : 64 'C ( Closed cup )
8.2.3 Lower Explosion Limits : 0.6 Vol. -%
8.2.4 Upper Explosion Limits : 11.2 Vol. -%
-----------------------------------------------------------------------------------------------------------------
9. STABILITY AND REACTIVITY
-----------------------------------------------------------------------------------------------------------------
9.1 Conditions to avoid :
When heated above flash point and / or with spraying or
atomization, a flammable mixture may form with air.
9.2 Materials to avoid :
(If appicable, information referring to individual components
of the product is given belows )
9.3 Hazardous decomposition products :
The product is supplied in a stable form, but if container left open
at room temperature or above, it will lose solvents by evaporation.
9.4 Further Information
-----------------------------------------------------------------------------------------------------------------
10. TRANSPORT INFORMATION
-----------------------------------------------------------------------------------------------------------------
Dangerous goods regulations
10.1 Land transport ADR / RID
( interstate / intrastate)
Not restricted
10.2 Inland Navigation ADN
For inland navigation consulation necessary :
10.3 Sea transport IMDG
IMDG : Class 9 UN-No. 3062 PG III
Marine Pollutant : Yes
EMS : ---- MFAG : ----
Technical name refer to UN-No. :
Enviromentally hazardous substance, liguid, n.o.s. *
Hazardous substance :
Aromatic solvents naphtha, MMB, EB Acetat
10.4 Air transport ICAO-YI and IATA-DGR
Not restricted.
------------------------------------------------------------------------------------------------------------------
11. REGULATORY INFORMATION
------------------------------------------------------------------------------------------------------------------
Fallow all reguration in your country.
------------------------------------------------------------------------------------------------------------------
12. OTHER INFORMATION
------------------------------------------------------------------------------------------------------------------
Reference
Kocosol #150 MSDS. SK Corp.
Methyl Methoxy Butanol MSDS. KURARAY CO.,LTD.
MATERIAL SAFETY DATA SHEET ( DATA PREPARED: 1996.9.10 )
=====================================================
BRAND : SILICOAT KSC-1500
------------------------------------------------------------------------------------------------------------------
1. COMPOSITION / INFORMATION ON INGREDIENTS
------------------------------------------------------------------------------------------------------------------
Common Name----------------------CAS-No.---------------- %
Solvents Naphtha, Aromat-----CAS-No. 64742-95-6-----40~60%
Acrylic Resin-----CAS-No. 9003-63-8-----30~35 %
Phthelate C16H22O4------CAS-No. 1322-94-7-----5~20 %
The manufacturers reserve the right to alter and improve the specifications without notice.
-------------------------------------------------------------------------------------------------------------------
2. Hazards Identification
-------------------------------------------------------------------------------------------------------------------
INHALATION :
EYE CONTACT : Irritating to eyes
SKIN CONTACT: Irritanting to skin
------------------------------------------------------------------------------------------------------------------
3. FIRST AID MEASURES
------------------------------------------------------------------------------------------------------------------
3.1 General Remarks :
Bring affected person out of danger area.
Place person on side instable position if unconscious.
Employ mouth-to-mouth resuscitation if breathing ceases.
3.2 Inhalation :
Bring affected person outside and ensure that he/she is comfortable.
Employ mouth-to-mouth resuscitation if breathing ceases.
3.3 Skin contact :
On skin contact, rinse thoroughly with water.
With continous skin irritation, consult doctor.
3.4 Eye Contact
Rinse thoroughtly immediately for at least 5 minutes keeping eyelid open,
Further treatment by eye doctor.
3.5 Ingestition :
Supply with medical care.
-----------------------------------------------------------------------------------------------------------------
4. FIRE-FIGHTING MEASURES
-----------------------------------------------------------------------------------------------------------------
4.1 Suitable extinguishing media :
Usual measures for chemical fires.
4.2 Extinguishing media which must be used for safety reasons
4.3 Special exposure hazards arising from the substance or
preparation itself, combustion products, resulting gases :
Formation of flammable or explosive vapour / air mixtures possible.
Danger of explosion with fire.
Do not inhale explosive gases or smoke fumes.
4.4 Special protective equiptment for fire fighters :
------------------------------------------------------------------------------------------------------------------
5. ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------------------------------------------------------------
5.1 Personal Precautions :
Keep person at a distance and stay on them weather side.
5.2 Environmental Precautions :
Dispose of waste in accordence with the legal regulations
issued by the appropriate local and national authorities
5.3 Methods of cleaning up :
Absorb with liquid-binding material (e.g. sand, infusorial earth, inert absorbent ).
5.4 Further Information :
Remove all sorces of ignition.
----------------------------------------------------------------------------------------------------------------
6. HANDLING AND STORAGE
----------------------------------------------------------------------------------------------------------------
6.1 Handling :
No dangerous reactions are known to occur with correct handling and storage.
The product should only be handling by trained personel.
6.2 Storage :
Fumes may be released in closed storage rooms or during processing.
Keep containes dry and tightly sealed-even empties.
The product is water dangering.
-----------------------------------------------------------------------------------------------------------------
7. EXPOSURE CONTROLS / PERSONAL PROTECTION
----------------------------------------------------------------------------------------------------------------
7.1 Additional instructions for technical installation.
Eventual aspiration in case of solvent fumes. Technical protection
measures have always priority over personal protection equipment.
7.2 Ingredients with threshold limit values :
Values of maximum admissible concentration :
500 ppm referring to Solvents Naphtha, Aromat
7.3 Personal Protection
7.3.1 General Protection :
Wash face / hands before break and of work.
7.3.2 Respiratory Protection :
If maximum admissible concentration value at the workplace is
exceeded or you feel trouble, apply respirator with charchol filter.
7.3.3 Eye Protection :
Wear safety goggles with side-shields ( if handling large amounts )
7.3.4 Skin Protection :
Preventive skin protection recommended.
7.3.5 Hand Protection :
Wear protective glove made of solvent-resistent material ( if handling large amounts )
--------------------------------------------------------------------------------------------------------------------
8. PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------------------------------------------------
8. Physical and chemical properties
8.1 Appearance
8.1.1 Physical state : Fluid
8.1.2 Colour : COLOURLESS or Characteristic
8.1.3 Odour : Characteristic
8.2 Data relevant to safety
8.2.1 Viscosity : ( 25 'C ) -> 11~17.5 Storkes
8.2.2 Flash Point : 42.2 'C ( Closed cup )
8.2.3 Lower Explosion Limits : 1.0 Vol. -%
8.2.4 Upper Explosion Limits : 5.2 Vol. - %
-----------------------------------------------------------------------------------------------------------------
9. STABILITY AND REACTIVITY
-----------------------------------------------------------------------------------------------------------------
9.1 Conditions to avoid :
When heated above flash point and / or with spraying or
atomization, a flammable mixture may form with air.
9.2 Materials to avoid :
(If applicable, information referring to individual components
of the product is given below )
9.3 Hazardous decomposition products :
The product is supplied in a stable form, but if container left open
at room temperature or above, it will lose solvents by evaporation.
9.4 Further information :
-----------------------------------------------------------------------------------------------------------------
10. TRANSPORT INFORMATIOIN
-----------------------------------------------------------------------------------------------------------------
Dangerous goods regulations
RID/ADR/IMDG-Code/ICAO-TL
10.1 Land transport ADR / RID
(interstate / intrastate)
Not restricted
10.2 Inland navigation ADN
For inland navigation consulation necessary :
10.3 Sea transport IMDG
IMDG : Class 9 UN-No. 3062 PG III
Marine pollutant : Yes
EMS : ---- MFAG : ----
Technical name refer to UN-No. :
Enviromentally hazardous substance, liquid, n.o.s. *
Hazardous substance :
Aromatic solvents nephtha.
10.4 Air transport ICAO-YI and IATA-DGR
Not restricted.
-----------------------------------------------------------------------------------------------------------------
11. REGULATORY INFORMATION
-----------------------------------------------------------------------------------------------------------------
Fallow all reguration in your country.
----------------------------------------------------------------------------------------------------------------
12. OTHER INFORMATION
----------------------------------------------------------------------------------------------------------------
Reference
Kocosol #100 MSDS. SK Corp.
* GENERAL INFORMATION
-------------------------------------------
GENERAL HINTS
This method is developed to decorate the surface of aluminum, steel, brass and
wood etc..., which are changed in quality or burnt off by high temp. (above 300 'C)
This method is applied to decorating the surface of small size goods like key board,
lighter, kitchen utensils, helmet or wood furniture.
This method is especially useful for decorating aluminum surface of kitchen cooker
because of high heat resistance. ( about 200 'C )
Making transfer paper is not different from making ceramic Decal paper except ink and
over printing lacquer ( Covercoat ).
This method is peeling off the over printing lacquer film from the transfered picture adhered
onto surface of object.
MATERIALS
COLOR INK : STARPOL BK-3101--------BK-3699
SKIM COAT : STARPOL BK-3100 ( CLEAR )
OVER PRINTING LACQUER :
SLICOAT SC-1500 ( CLEAR )
SLICOAT SB-1500 ( BLUE )
* METHOD OF MAKING TRANSFER PAPER
---------------------------------------------------------------------
SELECTION OF BASE PAPER
Generally used the metapaper for ceramic transfer paper.
COLOR PRINTING
Make the proper color by mixing or directly from STAPOL BK-3101 ---- BK-3699
and print by screen process.
The screen is used usually 150 ~ 250 mesh.
SKIM COAT ( BK-3100 CLEAR )
Print full surface of picture with BK-3100 CLEAR by 150 ~ 200 mesh silk screen.
Drying time : 4 ~ 8 Hrs.
The SKIM COAT is not always necessary, but the picture is concerned to be broken
by thin color printing, SKIM COAT is necessary.
OVER PRINTING LACQUER (SLICOAT)
Coat SLICOAT ( SC-1500 or SB-1500 ) on the picture thicker than general ceramic coating
thickness.
If the surface of object is concerned to be contaminated by dye stuff, SC-1500 must be used.
Recommended dry film thickness : 30 Micron
Drying time : About 8 Hrs.
STORAGE OF THE PICTURES
For storing the ready transfer picture sheets, inbetween paper will be necessary under
extereme influence of pressure or within high room temperature, and the sheets must be
always kept flat without crumpled or folded up.
* APPLICATION OF TRANSFER PAPER ONTO THE OBJECT
-------------------------------------------------------------------------------------------------
APPLICABLE OBJECT
Most of all objects are possible to be decorated except plastics.
( Ex. : PE, PP, ABS, PVC and Etc... )
Main applicable objects are uncoated and coated ( Heat cured lacquer ) aluminum,
steel and brass surfaces.
Another applicable object is coated wood surface.
CLEANING OF SURFACE
Clean the surface without any oils, grease and dirts.
STICKING OF TRANSFER FILM
The same as general ceramic transfer film.
PEELING OFF THE SLICOAT FILM
Dry well the sticked transfer film for 4 ~ 8 hours and then peel off the SLICOAT FILM.
If drying time is necessary to be shorten, heat the object 100 'C x 30 mins.
and peel off the film after cooling the object to mild temperature.
CLEANING OUTSIDE OF THE PICTURE
After peel off the SLICOAT FILM, clean carefully the dirts outside of the picture by wet cloth.
CURING
HEAT RESISTANT OBJECT ( ALUMINUM, STEEL, AND ETC... )
BAKES 180'C x 30 MINS. OR 200'C x 15 MINS.
WOOD MUST BE SPRAY COATED WITH WOOD LACQUER ONTO THE PICTURE.
* BK-3000 SERIES TECHNICAL INFORMATION
GENERAL PROPERTIES OF CURED INK
-------------------------------------------------------------------------
OBJECT : ALUMINUM PLATE
PRINTING CONDITION : SKIMCOAT COVERED
BAKING SCHEDULE : 180'C x 30 MINS.
PENCIL HARDNESS : UP TO 4H
CROSS CUT : 100 / 100
FLEXIBILITY : 1/8 INCH PASS
IMPACT RESISTANCE : 1/4 INCH x 500G x 25 CM PASS.
HEAT RESISTANCE
200'C x 24 HRS. : SLIGHT YELLOW
BOILING WATER RESISTANCE,
100'C x 24 HRS. : NO CHANGE
DETERGENT RESISTANCE, 25'C x 24 HRS.
5% SYNTHETIC DETERGENT : NO CHANGE
5% SOAP : NO CHANGE
ACID RESISTANCE, 25'C x 24 HRS.
5% HCI : NO CHANGE
5% ACETIC ACID : NO CHANGE
ALKALI RESISTANCE, 25'C X 24 HRS.
5% NaOH : NO CHANGE
Thank you for your kind attention.
With Best Regards,
Jim Kim
Sung Do International Co.,Ltd.
502-1, Mok-Dong, Yang Churn-Gu, Seoul, 158-807, Korea.
Tel : (82)(2) 2652-9482 / 9483
Fax : (82)(2) 2651-5648
Homepage : http://www.ec21.com/sdicom
